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Palazzo Serra di Cassano is a building in Naples, Italy. It is behind Piazza del Plebiscito on via Monte di Dio, the road leading up to the height of Pizzofalcone. The building is from the first half of the 1700s and represents the finest in the tradition of Neapolitan urban architecture. It was built by Ferdinando Sanfelice, also responsible for the construction of the nearby Nunziatella, the Bourbon military academy in the days of the Kingdom of Naples.